Hydrophobic, Highly Conductive Ambient-Temperature Molten Salts
نویسندگان
چکیده
منابع مشابه
Polarography in Molten Salts
TYPES OF MELTS From the practical viewpoint, melts may be classified according to melting points which may limit the available techniques. The lowest melting, with working temperatures up to 250°, are typified by the LiNO3—NaNO3— KNO3 eutectic, NaNO3—KNO3 eutectic, LiClO4, and ammonium formate. With these solvents it is possible to use the dropping mercury electrode, or hanging mercury drop ele...
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In a continued effort to improve the suitability of ionic liquids in applications operating at raised temperatures, novel spirocyclic 'azoniaspiro' salts (with cations derived from five-, six-, seven- and eight-membered rings) are prepared and characterised. The structural and thermal properties of these salts are compared against those of established analogues. The stable geometries and ion pa...
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The work on molten salts and isotope separation performed over the years at Université Pierre et Marie Curie and at Collège de France is critically reviewed. This research, closely related to A. Klemm’s pioneering contributions, leads among other things to the discovery of the effect now called the ‘Chemla effect’, after the late Professor Marius Chemla. These studies of ionic motions in melts,...
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The equivalent conductivity of molten salts containing more than two ion constituents will be discussed using the equivalent fractions (Äquivalentanteile). The ionic conductivities of the ion constituents follow from this equivalent conductivity and the transport numbers. The electrical transport phenomena are referred to the idealized ionic melt which is defined by the limiting values of the i...
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 1998
ISSN: 0020-1669,1520-510X
DOI: 10.1021/ic971286k